Hi Mustapha
There are three basic ways to record a cost (expense) of running your business:
I. Enter a bill from the Supplier (Purchases>Create Bill) to one of the expense headings you quote, to be paid off from the bak at a later date;
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Record a payment from your bank account directly to an expense heading;
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Record the fact that say a director or employee has paid for an expense out of their own funds and then want to reclaim that from the company, under Purchases>Expenses.
I think you are talking about 3.
In all cases, the record should show who the original supplier was, even in 3, eg I go to Tescos to buy some stationery, then reclaim the expense under 3.
Best you have a read though the various guides under "Need Help" to get the bigger picture to this and/or arrange some training.